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Nylon and polyamide are similar artificial fibers, which can be used to reinforce yarn for socks, but acrylic and polyester are two other different artificial fibers, that are not as wear resistant. I learned about fibers in fashion school. From personal experience, silk blend socks feel lovely, but don't wear as well as those with nylon or polyamide. Most yarns marketed as sock yarn already contain a percentage of nylon, but you can carry along a strand of wooly nylon thread with yarns that don't have any. I've made a few pair, but they're not old enough to determine longevity.
 
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