Salt is used in modern "steam" irons because it causes the water to create steam/vapor at a lower temperature. This is important for tailors, for example, who work with natural fibers and need to have the steam occur at the normal temperature that it occurs. Modern irons and steamers often have agents inside that do the same thing that the salt does, i.e., cause the water to create steam/vapor at a lower temperature.
It is more and more difficult each day to find the old steam irons like the ones that tailors use that heat the water to the temperature needed to create steam. Likewise, it is more and more difficult to find the old irons that have a flat sole plate with no steam vents--tailors and couture designers use damp press cloths and irons with flat sole plates to mold and shape fabric as they put garments together. Sometimes sleeves are set in by first using basting to partially shape, then they are draped over a "ham" and then draped with a damp press cloth after which heat is applied by an iron with a flat sole plate. Then the sleeve is left for at least a day to completely dry so that it won't get pulled out of shape when lifted off the ham while still retaining any dampness. Irons that have steam vents and produce "real" steam are used in a similar manner--shape is built into different parts of the couture garment by draping it in a certain way and then applying steam or a combination of steam and weight, and then left to completely dry before moving.
Before omitting the salt, I would make sure that the iron was guaranteed to withstand the higher heat needed to create the vapor or steam.